Demonstrates defluorinative cross-coupling in polyfluoroarenes, suggesting new catalytic methods.
Visible-light-induced excited-state palladium catalysis enables defluorinative C(sp 2 )-C(sp 2 ) cross-coupling of polyfluoroarenes with aryl boronic acids under blue LED irradiation at room temperature. The Pd(OAc) 2 /BrettPhos catalyst selectively activates C(sp 2 )-F bonds without external...
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Dey et al. (2026) studied this question.
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