Designing Copper‐Based Catalysts for Efficient Carbon Dioxide Electroreduction

The electroreduction of carbon dioxide (CO₂ ) has been emerging as a high- potential approach for CO₂ utilization using renewables. When copper (Cu) based catalysts are used, this platform can produce multi-carbon (C₂₊ ) fuels and chemicals with almost net-zero emission, contributing to the closure of the anthropogenic carbon cycle. Nonetheless, the rational design and development of Cu-based catalysts are critical toward the realization of highly selective and efficient CO₂ electroreduction. In this review, first the latest advances in Cu-catalyzed CO₂ electroreduction in the product selectivity and electrocatalytic activity are briefly summarized. Then, recent theoretical and mechanistic studies of CO₂ electroreduction on Cu-based catalysts are investigated, which serve as programs to design catalysts. Strategies for devising Cu catalysts that aim at promoting different key elementary steps for hydrocarbon and C₂₊ oxygenates production are further summarized. Moreover, challenges in understanding the mechanism, operando investigation of Cu catalysts and reactions, and systems' influences are also presented. Finally, the future prospects of CO₂ electroreduction are discussed.