Efficient Heterostructures of Ag@CuO/BaTiO₃ for Low-Temperature CO₂ Gas Detection: Assessing the Role of Nanointerfaces during Sensing by Operando DRIFTS Technique

Tetragonal BaTiO₃ spheroids synthesized by a facile hydrothermal route using Tween 80 were observed to be polydispersed with a diameter in the range of ∼15-75 nm. Thereon, BaTiO₃ spheroids were decorated with different percentages of Ag@CuO by wet impregnation, and their affinity toward carbon dioxide (CO₂) gas when employed as sensitive layers in a microsensor was investigated. The results revealed that the metal nanocomposite-based sensor had an exceptional stability and sensitivity toward CO₂ gas (6-fold higher response), with appreciable response and recovery times (<10 s) and higher repeatability (98%) and accuracy (96%) at a low operating temperature of 120 °C, compared to those of pure BaTiO₃ and CuO. Such improved gas-sensing performances even at a very low concentration (∼700 ppm) is attributable to both the chemical and electrical contributions of Ag@CuO forming intermittent nanointerfaces with BaTiO₃ spheroids, exhibiting unique structural stability. The CO₂-sensing mechanism of CuO/BaTiO₃ nanocomposite was studied by the diffuse reflectance infrared Fourier transform spectroscopy technique that established the reaction of CO₂ with BaO and CuO to form the respective carbonate species that is correlated with the change in material resistance consequently monitored as sensor response.