Titanium (Ti)-based MOFs are promising materials known for their porosity, stability, diverse valence states, and a lower conduction band (CB) than Zr-MOFs. These features support stable ligand-to-metal charge transfer (LMCT) transitions under photoirradiation, enhancing photocatalytic performance. However, Ti-MOF structures remain a challenge owing to the highly volatile and hydrophilic nature of ionic Ti precursors. The discovery of MIL-125 marked a breakthrough in Ti-cluster coordination chemistry. Combining it with NH2 chromophores to form NH2-MIL-125 enhanced its structural design and extended its activity into the visible light region. This review delves into the high-performance photocatalytic properties of NH2-MIL-125, focusing on its applications in H2O2 and H2 production, CO2 and N2 reduction, drug and dye degradation, photocatalytic sensors, and organic transformation reactions. The discussion considers the influence of the Ti precursor, coordination environment, synthesis process, and charge transfer mechanisms. Numerous strategic methods have been discussed to improve the performance of NH2-MIL-125 by incorporating linker modification, metal node modification, encapsulation of active species, and post-modification for enhancing light absorption ability, promoting charge separation, and improving photocatalytic efficiency. Moreover, future perspectives include methods to investigate how the efficiency of NH2-MIL-125-based materials can be planned in promoting research by highlighting their versatility and potential impacts in the area of photocatalysis.
Priyadarshini et al. (Wed,) studied this question.