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Experimental study demonstrates efficient metal-free photocatalytic dehydrogenation of N-heterocycles using porphyrin polymers, suggesting a sustainable route to unsaturated heteroarenes.
The prepared imidazole-linked porphyrin-based conjugated microporous polymers enable efficiently photocatalytic oxidative dehydrogenation of N-heterocycles under mild conditions, yielding unsaturated N-heteroarenes with high yield.
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Chen et al. (2021) studied this question.
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