Thiobenzoic Acid-Catalyzed Regioselective Functionalization of Allylamines via Hydrogen Atom Transfer under Visible Light Irradiation

Masashi Fujita; Kaichi Watanabe; Riku Osanai; Kenji Yamashita; Hiromichi Egami; Yoshitaka Hamashima

doi:10.1039/d6qo00237d

January 1, 2026Organic Chemistry Frontiers

Thiobenzoic Acid-Catalyzed Regioselective Functionalization of Allylamines via Hydrogen Atom Transfer under Visible Light Irradiation

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Key Points

The aim is to explore selective transformations of allylamines through a new reaction pathway.
Used thiobenzoic acid as a catalyst.
Applied hydrogen atom transfer mechanism.
Utilized visible light irradiation as an energy source.
Achieved regioselective functionalization of allylamines.
Demonstrated effectiveness of the catalyst under light exposure.
Showed potential for synthesizing bioactive compounds with high selectivity.

Implication

Research demonstrates regioselective functionalization of allylamines using thiobenzoic acid, suggesting an innovative catalytic method.

Abstract

Since allylamines are easily accessible and can serve as key intermediates in the synthesis of bioactive compounds, selective transformations are extremely useful. So far, however, reactions of allylamines via hydrogen...

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Cite This Study

Fujita et al. (2026) studied this question.

synapsesocial.com/papers/69df2c88e4eeef8a2a6b1ab5 https://doi.org/10.1039/d6qo00237d

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Thiobenzoic Acid-Catalyzed Regioselective Functionalization of Allylamines via Hydrogen Atom Transfer under Visible Light Irradiation

Key Points

Implication

Abstract

Discussion

Cite This Study

Thiobenzoic Acid-Catalyzed Regioselective Functionalization of Allylamines via Hydrogen Atom Transfer under Visible Light Irradiation

Key Points

Implication

Abstract

Discussion

Cite This Study

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