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Four new DTS-BTD copolymers (P1-P4) differing by the concentration of electron-donating and -withdrawing substituents along the backbone have been synthesized and characterized by 2D-WAXS and in bottom-contact FETs. While all copolymers can self-assemble into lamellar superstructures, only P2 and P4 show a propensity to pi-stack. P4 exhibits a hole mobility as high as 0.02 cm(2) V(-1) s(-1) in excellent agreement with the close pi-stacking and lamellar distances found by structural analysis (0.36 and 1.84 nm, respectively) and absorbs homogenously across the entire visible spectrum as solar cell applications require.
Beaujuge et al. (2009) studied this question.