Solvent-Free CO₂ Capture Using Membrane Capacitive Deionization

Capture of CO₂, originating from both fossil fuels, such as coal combustion, and from renewables, such as biogas, appears to be one of the greatest technological challenges of this century. In this study, we show that membrane capacitive deionization (MCDI) can be used to capture CO₂ as bicarbonate and carbonate ions produced from the reaction of CO₂ with water. This novel approach allows capturing CO₂ at room temperature and atmospheric pressure without the use of chemicals. In this process, the adsorption and desorption of bicarbonate ions from the deionized water solution drive the CO₂(g) absorption-desorption from the gas phase. In this work, the effects of the current density and the CO₂ partial pressure were studied. We found that between 55 and 75% of the electrical charge of the capacitive electrodes can be directly used to absorb CO₂ gas. The energy requirement of such a system was found to be ≈40 kJ mol⁻¹ at 15% CO₂ and could be further improved by reducing the ohmic and non-ohmic energy losses of the MCDI cell.