Hollow Metal–Organic‐Framework‐Mediated In Situ Architecture of Copper Dendrites for Enhanced CO₂ Electroreduction

Electrocatalytic reduction of CO₂ to a single product at high current densities and efficiencies remains a challenge. However, the conventional electrode preparation methods, such as drop-casting, usually suffer from low intrinsic activity. Herein, we report a synthesis strategy for preparing heterogeneous electrocatalyst composed of 3D hierarchical Cu dendrites that derived from an in situ electrosynthesized hollow copper metal-organic framework (MOF), for which the preparation of the Cu-MOF film took only 5 min. The synthesis strategy preferentially exposes active sites, which favor's the reduction of CO₂ to formate. The current density could be as high as 102.1 mA cm⁻² with a selectivity of 98.2 % in ionic-liquid-based electrolyte and a commonly used H-type cell.