Synthesis of Mesoporous Ag₂O/SnO₂ Nanospheres for Selective Sensing of Formaldehyde at a Low Working Temperature

Formaldehyde (HCHO) is a prevalent indoor gas pollutant that has been seriously endangering human health. Developing semiconductor metal oxide (SMO) gas sensors for selective measurement of formaldehyde at low working temperatures remains a great challenge. In this work, silver/tin-polyphenol hybrid spheres are applied as a sacrificial template for the fabrication of spherical mesoporous Ag₂O/SnO₂ sensing materials. The obtained mesoporous Ag₂O/SnO₂ spheres have a uniform particle size (∼80 nm), large pore size (5.8 nm), and high specific surface area (71.3 m² g⁻¹). The response is 140 toward formaldehyde (10 ppm) at a low working temperature (75 °C). The detection limit reaches a low level of 23.6 ppb. Most importantly, it has excellent selectivity toward interfering gases. When the concentration of the interfering gas (e.g., ethanol) is 5 times as high as that of formaldehyde, the response is little affected. Theoretical calculations suggest that the addition of Ag₂O can significantly enhance the adsorption energy toward formaldehyde, thus improving formaldehyde sensing performance. This work demonstrates an efficient self-template synthesis strategy for noble metal catalyst-decorated mesoporous metal oxide spheres, which could boost gas sensing performance at a lower working temperature.