Very large-scale integration of devices in a circular pattern has several advantages over the commonly used rectangular grid layout. For the development of such integrated circuits on a 2D semiconductor platform, spontaneous growth of the material in the form of circular islands is desirable. Here, we report the natural formation of 1L-MoS2 circular islands of diameter as large as a few hundreds of micrometers on SiO2/Si substrates by the chemical vapor deposition (CVD) technique without the use of any seeding layer. The size of the circles is found to increase with the amount of sulfur used during growth. The study reveals that these circular islands are formed with a less-defective interior and a more defective outer part that is dominated by a large density of grain boundaries and twists. Due to the lower defect density, the interior region yields much higher photoluminescence than the peripheral part. Field effect transistors (FETs) are fabricated on the inner and outer portions of a circle to estimate the mobility and concentration of the background carriers in the two regions. The study shows that the maximum mobility is more than double in the interior than in the outer part, while the carrier concentration remains practically unchanged in the two regions. The natural tendency to minimize the strain energy resulting from the mismatch between the thermal expansion coefficients of the monolayer and the substrate and the edge energy that originates from the boundary tension is thought to be the driving force behind the formation of these circular domains.
Patra et al. (Tue,) studied this question.