This analysis demonstrates conformational isomerizations of thymol and carvacrol in a nitrogen cryomatrix, indicating significant changes in their energy profiles.
Thymol (2-isopropyl-4-methylphenol) and carvacrol (5-isopropyl-2-methylphenol) differ only in the relative positions of the hydroxyl and alkyl substituents, yet this subtle change reverses their torsional energy profiles: in thymol, isopropyl rotation...
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Duarte et al. (2026) studied this question.
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