What question did this study set out to answer?

The aim is to explore the synthesis and unique reactions of a nickel bis(hydridogermylene) complex.

April 19, 2026Chemical Communications0 citationsOpen Access

GeII -H/SiIV -H dehydrocoupling and cycloaddition chemistry of a Ni0 bis(hydridogermylene) complex

THTerrance J. HadlingtonAustralian Regenerative Medicine Institute ESEmeric SchubertMunich University of Applied Sciences

Key Points

The aim is to explore the synthesis and unique reactions of a nickel bis(hydridogermylene) complex.
Synthesize bis(hydridogermylene) complex
Investigate GeII-H/SiIV-H dehydrocoupling reactions
Characterize final products
Successfully synthesized a high-yielding bis(hydridogermylene) complex of Ni0
Observed a distinctive GeII-H/SiIV-H dehydrocoupling reaction
Formed unique η3-[Ge2Si]-Ni products

Abstract

We report the high-yielding synthesis of bis(hydrido-germylene) complex of Ni0 (2). In contrast to known hydrido-tetrylene chemistry, this complex demonstrates a unique GeII-H/SiIV-H dehydrocoupling reaction, in formation of an η3-Ge2Si-Ni...

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