Models suggest substrate orientation directs sulphur oxidation versus hydrogen abstraction reactions in non-haem iron enzymes.
Active metallopeptide based mimics of substratebound cysteine dioxygenase (CDO) and isopenicillin-N-synthase (IPNS) suggest that differential reactivity between the two metalloenzymes results from the orientation of a chemically active S(3pπ) dominated...
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Shearer et al. (2026) studied this question.
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