Formation of Ti-Cu-Ni Intermetallic Coatings on Titanium by Laser Processing of an Explosively Welded Layered Composite

This study investigates the influence of design factors and key process parameters—including explosive welding (EXW), rolling, and laser processing—on the formation, microstructure, and tribological properties of Ti–Cu–Ni intermetallic coatings. A combined manufacturing approach was employed, starting with the EXW of an MN19 cupronickel alloy to a VT1-0 titanium substrate, followed by multi-pass rolling to achieve a cladding thickness of approximately 0.3 mm. Subsequently, laser surface remelting was performed to facilitate controlled mass transfer and homogenization within the reaction zone. Numerical simulation using COMSOL Multiphysics v. 5.4 was utilized to optimize the thermal cycles and determine the ideal energy density (42 J/mm2) for phase formation. The results demonstrate that the primary structural components of the coatings produced under optimal conditions are solid solutions based on the ternary-modified titanium cuprides Ti2Cu(Ni) and TiCu(Ni). The transition from a layered bimetal to a finely dispersed intermetallic structure significantly enhances the surface characteristics. This specific phase composition provides a sustained microhardness of ~5 GPa across the coating cross-section. Comparative wear tests against fixed abrasive revealed that the wear resistance of the Ti–Cu–Ni coatings is 2.5 times higher at room temperature and 1.5 times higher at 600 °C than that of the base VT1-0 titanium.