A Multifunctional Bismuth-based Metal-Organic Framework with Record-High Porosity, Rare Topology, and Efficient Visible-Light Photocatalysis

Michelle Åhlén; Ha Phan; Mariusz Kubus; James N. McPherson; Francoise M. Amombo Noa; Maria Strømme; Kasper S. Pedersen; Lars Öhrström; Ocean Cheung

doi:10.1039/d6ta01278g

January 1, 2026Journal of Materials Chemistry AOpen Access

A Multifunctional Bismuth-based Metal-Organic Framework with Record-High Porosity, Rare Topology, and Efficient Visible-Light Photocatalysis

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Key Points

This research aims to develop a highly porous bismuth-based metal-organic framework for photocatalytic applications.
Constructed a bismuth-based metal-organic framework (UU-206) using Bi(NO3)3·5H2O and a specific octacarboxylate linker.
Characterized the framework's structure and properties, particularly its porosity and photocatalytic efficiency.
UU-206 exhibits record-high porosity compared to existing frameworks.
Demonstrates effective visible-light photocatalytic activity for targeted reactions.
Uncovers unique topology of the framework, contributing to its efficiency.

Implication

Shows efficient visible-light photocatalysis in bismuth frameworks, implying potential industrial applications.

Abstract

Here, we report the bismuth-based metal-organic framework (MOF), UU-206, constructed from Bi(NO3)3·5H2O and an extended tetraphenylenethylene-cored octacarboxylate linker (H8ettb). UU-206 crystallizes as a three-dimensional framework that can be described by...

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Cite This Study

Åhlén et al. (2026) studied this question.

synapsesocial.com/papers/69ec5a2588ba6daa22dabae6 https://doi.org/10.1039/d6ta01278g

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A Multifunctional Bismuth-based Metal-Organic Framework with Record-High Porosity, Rare Topology, and Efficient Visible-Light Photocatalysis

Key Points

Implication

Abstract

Discussion

Cite This Study

A Multifunctional Bismuth-based Metal-Organic Framework with Record-High Porosity, Rare Topology, and Efficient Visible-Light Photocatalysis

Key Points

Implication

Abstract

Discussion

Cite This Study

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