MOF-Derived In₂O₃ Microrods for High-Performance Photoelectrochemical Ultraviolet Photodetectors

Ultraviolet photodetectors (UV PDs) have attracted extensive attention owing to their wide applications, such as optical communication, missile tracking, and fire warning. Wide-bandgap metal-oxide semiconductor materials have become the focus of high-performance UV PD development owing to their unique photoelectric properties and good stability. Compared with other wide-bandgap materials, studies on indium oxide (In₂O₃)-based photoelectrochemical (PEC) UV PDs are rare. In this work, we explore the photoresponse of In₂O₃-based PEC UV PDs for the first time. In₂O₃ microrods (MRs) were synthesized by a hydrothermal method with subsequent annealing. In₂O₃ MR PEC PDs have good UV photoresponse, showing a high responsivity of 21.19 mA/W and high specific detectivity of 2.03 × 10¹⁰ Jones, which surpass most aqueous-type PEC UV PDs. Moreover, In₂O₃ MR PEC PDs have good multicycle and long-term stability irradiated by 365 nm. Our results prove that In₂O₃ holds great promise in high-performance PEC UV PDs.