What question did this study set out to answer?

This research aims to develop a transmetalation strategy to synthesize sulfonamide-functionalized palladium(II) and platinum(II) dithiocarbamate complexes.

April 27, 2026Inorganic Chemistry

Overcoming Kinetic Inertness via Transmetalation: Nickel-Mediated Synthesis of Sulfonamide-Functionalized Pd II and Pt II Dithiocarbamates

View Full Paper

Ask AI

Bookmark

Authors

EIEugene V. IgnatovAltai State University ЛЗЛев Е. ЗеленковITMO University SBSergey V. BaykovSt Petersburg University

Discussion

Member takes

Implication

Randomized trial demonstrates a transmetalation strategy to synthesize sulfonamide complexes in group 10 metals, indicating enhanced accessibility.

Key Points

This research aims to develop a transmetalation strategy to synthesize sulfonamide-functionalized palladium(II) and platinum(II) dithiocarbamate complexes.
Utilized kinetically labile nickel(II) dithiocarbamates as transmetalation precursors.
Synthesized two families of chelate complexes: N,S,S,S-tetradentate and N,S,S,N-tetradentate.
Scaled the procedure to gram quantities and characterized structures using X-ray crystallography.
Synthesis of sulfonamide-functionalized ML(NSCN) (M = Pd, Pt) species achieved.
X-ray crystallography of 19 structures showed C-S bond lengths averaging 1.76 Å and 1.71 Å.
Revealed significant contributions from dithiocarbamate and thioureide resonance structures.

Cite This Study

Ignatov et al. (2026) studied this question.

synapsesocial.com/papers/69eefcaefede9185760d3a47 https://doi.org/10.1021/acs.inorgchem.6c00811

View Full Paper

Ask AI

Bookmark

Implication

Randomized trial demonstrates a transmetalation strategy to synthesize sulfonamide complexes in group 10 metals, indicating enhanced accessibility.

Overcoming Kinetic Inertness via Transmetalation: Nickel-Mediated Synthesis of Sulfonamide-Functionalized Pd II and Pt II Dithiocarbamates

Discussion

Member takes

Implication

Key Points

Cite This Study

Overcoming Kinetic Inertness via Transmetalation: Nickel-Mediated Synthesis of Sulfonamide-Functionalized Pd II and Pt II Dithiocarbamates

Discussion

Member takes

Implication

Key Points

Cite This Study

Also Consider

Also Consider