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This research aims to synthesize polymeric subporphyrin materials to explore their unique properties and potential applications.

Subporphyrin Frameworks: A Missing Link Between Porphyrinoids and Porous Aromatic Networks

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Innovative materials demonstrate enhanced light harvesting and catalytic efficiency, suggesting new applications in photocatalysis.

This research aims to synthesize polymeric subporphyrin materials to explore their unique properties and potential applications.
Synthesis of porous aromatic networks PAF-HNU1 and PAF-HNU2 by coupling meso-functionalized subporphyrins with rigid aromatic linkers under solvothermal conditions.
Characterization of photophysical properties and catalytic performance of the synthesized frameworks.
PAF-HNU2 exhibited two to three times higher catalytic efficiency in advanced oxidation reactions compared to PAF-HNU1 and porphyrin-based analogues.
The frameworks demonstrated extended π-delocalization and strong red-shifted absorption in the UV-vis-NIR region.

Zhao et al. (2026) studied this question.

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