C–N Bond Formation from Co-Conversion of N ₂ and CO ₂ Mediated by Nb ₂ OH ₄ – Cluster Anions: Importance of Hydride Ligands

Xiao‐Xiao Liu; Qing‐Yu Liu; Ziyu Li; Sheng‐Gui He

doi:10.1039/d6cp00218h

January 1, 2026Physical Chemistry Chemical Physics

C–N Bond Formation from Co-Conversion of N ₂ and CO ₂ Mediated by Nb ₂ OH ₄ – Cluster Anions: Importance of Hydride Ligands

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Key Points

This work aims to explore the construction of C–N bonds from nitrogen and carbon dioxide using specific cluster anions.
Utilized Nb2OH4 cluster anions for co-conversion of N2 and CO2.
Examined the role of metal hydrides in N2 activation and functionalization processes.
Identified the importance of hydride ligands in mediating reactions.
Showed potential pathways for improving efficiency in C–N bond formation.

Implication

This research demonstrates C–N bond formation using metal hydrides from N2 and CO2, suggesting new pathways for functionalization.

Abstract

Constructing C–N bonds directly from N 2 and CO 2 is highly desirable but challenging. Although metal hydrides show promise in N 2 activation and functionalization with CO 2 , their precise role in selectively...

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Cite This Study

Liu et al. (2026) studied this question.

synapsesocial.com/papers/69f154c0879cb923c494505a https://doi.org/10.1039/d6cp00218h

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C–N Bond Formation from Co-Conversion of N ₂ and CO ₂ Mediated by Nb ₂ OH ₄ – Cluster Anions: Importance of Hydride Ligands

Key Points

Implication

Abstract

Discussion

Cite This Study

C–N Bond Formation from Co-Conversion of N ₂ and CO ₂ Mediated by Nb ₂ OH ₄ – Cluster Anions: Importance of Hydride Ligands

Key Points

Implication

Abstract

Discussion

Cite This Study

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