Dynamic Covalent Switching between a 1,1’-Ruthenocene Macrocycle and a Ruthenocenophane through a Transimination Reaction

Max Roemer; Gilles Frison; Han Vinh Huynh

doi:10.1039/d6qi00665e

January 1, 2026Inorganic Chemistry FrontiersOpen Access

Dynamic Covalent Switching between a 1,1’-Ruthenocene Macrocycle and a Ruthenocenophane through a Transimination Reaction

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Key Points

This research explores the dynamic covalent switching of ruthenocene compounds through transimination reactions.
Investigated covalent dynamic chemistry
Constructed organic macrocycles and frameworks
Analyzed reactions involving amine and aldehyde building blocks
Identified structural transformations between ruthenocene macrocycle and ruthenocenophane
Demonstrated potential for versatile synthetic applications in organic frameworks

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Implication

Dynamic covalent chemistry facilitates structural changes in ruthenocene frameworks, suggesting versatile synthetic pathways.

Abstract

Dynamic covalent chemistry has been employed extensively for connecting amine and aldehyde building blocks to construct organic macrocycles, covalent organic frameworks, and organometallic analogues. However, detailed investigations on covalent dynamic...

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Roemer et al. (2026) studied this question.

synapsesocial.com/papers/69f2a4578c0f03fd67763478 https://doi.org/10.1039/d6qi00665e

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Dynamic Covalent Switching between a 1,1’-Ruthenocene Macrocycle and a Ruthenocenophane through a Transimination Reaction

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

Dynamic Covalent Switching between a 1,1’-Ruthenocene Macrocycle and a Ruthenocenophane through a Transimination Reaction

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

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