Demonstrates regioselective azo-saccharin synthesis in aryl sulfonimidoyl fluorides, suggesting a new approach for synthetic chemists.
Regioselective anionic [1,4] Fries-type rearrangement of aryl sulfonimidoyl fluorides unveils cryogenically stable aryl sulfonimidoyl fluoridate anions enabling stereospecific synthesis of aza-saccharins via SuFEx capture with inversion at sulfur.
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Leypold et al. (2026) studied this question.
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