H2O-Controlled Selective Disulfide Etherification and Thiocyanation of Pyrroles via Linear Paired Electrolysis

Key Points

• This research aims to develop a new method for selective disulfide etherification and thiocyanation of pyrroles using linear paired electrolysis.
• Utilized H2O-controlled linear paired electrolysis for reactions.
• Produced functionalized dipyrrolyl disulfides and thiocyanated pyrroles without additional solvents.
• Examined reaction conditions to optimize yields.
• Successfully synthesized a variety of dipyrrolyl disulfides.
• Demonstrated selective thiocyanation of pyrroles with high efficiency.
• Yielded significant functionalization of pyrrole derivatives.