Demonstrates enhanced photochemical properties in four-coordinate copper complexes, indicating potential in energy applications.
MLCT excited-state energy. This high triplet energy was used in a proof-of-principle upconversion process and triplet-triplet energy transfer photocatalysis. Our findings demonstrate how diisocyanide chelate ligands can be used to tune the photophysical and photochemical properties of photoactive copper(I) complexes with four-coordinate coordination environments.
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Eggenweiler et al. (2026) studied this question.
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