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April 30, 2026

Understanding low-pressure CO₂ insertion chemistry in epoxide-CO₂ copolymerization catalysis.

Rosie Thorogood Katharina H S Eisenhardt M A Smith Charlotte K Williams

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Key Points

This study aims to explore the insertion chemistry of low-pressure CO2 in the catalysis of epoxide-CO2 copolymerization.
Utilized various catalytic systems under low-pressure CO2 conditions.
Examined the efficiency and mechanism of copolymer formation.
Analyzed the impact of pressure and temperature on reaction outcomes.
Achieved significant enhancements in copolymer yields under low-pressure conditions.
Demonstrated a positive correlation between pressure and copolymerization efficiency.
Identified specific catalysts that markedly improved reaction kinetics.

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Implication

Demonstrates improved copolymerization efficiency in epoxide-CO2 systems, highlighting the importance of low-pressure conditions.

Abstract

Despite many CO

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Cite This Study

Thorogood et al. (2026) studied this question.

synapsesocial.com/papers/69f6e6478071d4f1bdfc6e1f https://doi.org/10.1038/s41557-026-02098-6

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