A Tunable Catadioptric Spectrometer with Bragg-Condition-Preserving Rotation for High-Resolution Spectroscopy

High-throughput and compact volume phase holographic (VPH) grating transmission spectrometers are widely employed in scientific research, agriculture, and industrial applications. Conventional transmission spectrometers generally adopt a fixed configuration and therefore have limitations in simultaneously achieving high spectral resolution and broad wavelength coverage. To address the limited tunability of transmission spectrometers, this work presents the theoretical analysis and experimental validation of a transmission spectrometer incorporating a novel catadioptric grating assembly, which consists of a transmitting VPH and a planar reflector. A catadioptric system is a combination of reflective (catoptric) and refractive (dioptric) elements. In the proposed configuration, a VPH grating and a plane mirror arranged at a fixed 90° angle form the catadioptric dispersion module. Synchronous rotation of this assembly enables wavelength scanning. The structure ensures that the diffracted ray along the optical axis of the imaging lens maintains the Bragg condition across the scanning range, thereby preserving maximum diffraction efficiency. The optical configuration and structural parameters of the spectrometer were theoretically derived, and a prototype spectrometer with an f-number of 1.8 employing a 2400 g/mm grating was constructed. Measurements demonstrate that, when the rotation angle is tuned from 30.5° to 50.5°, the accessible spectral range covers from 410 nm to 650 nm. Spectral response measurements using a tungsten–halogen light source confirm that the spectrometer maintains an acceptable diffraction efficiency across the entire tuning range. The measured spectral resolution is 0.1 nm at 626 nm with a 2400 g/mm grating and 0.18 nm with a 1500 g/mm grating. The spectrometer was further applied to fiber-enhanced gas Raman spectroscopy, where it successfully resolved the closely spaced Raman peaks of CH4 and C2H6 that are difficult to distinguish using conventional compact spectrometers. These results demonstrate that the proposed tunable catadioptric spectrometer simultaneously provides excellent wavelength tunability and high spectral resolution.