This research demonstrates regioselective arylation and alkylation of boronates, suggesting a step-economical method for functionalization.
)-H alkylation and arylation of unactivated alkyl boronates. This method enables a step-economical route to diverse functionalized boronates with good regioselectivity. Mechanistic studies suggest that the reaction proceeds through a sequential hydrogen atom transfer and 1,2-boryl migration pathway.
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Li et al. (2026) studied this question.
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