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Selective defluorination yields diphenyl(2,2,2-trifluoroethyl)phosphane, suggesting phosphide reagents are effective.
1,1,1,2-Tetrafluoroethane (HFC-134a), the most commonly used 3rd generation refrigerant, reacts with lithium phosphide reagents through selective defluorophosphination of the single C(sp 3 )-F bond to yield diphenyl(2,2,2-trifluoroethyl)phosphane. DFT calculations were used to...
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Warsame et al. (2026) studied this question.
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