To evaluate the potential of the XeF2/2Li[Al(ORF)4] system as a deelectronator.
Investigated the reaction system XeF2/2Li[Al(ORF)4] as an oxidant.
Analyzed the generation of organoxenonium intermediates.
Examined the formation of radical cations from substrates.
Successful generation of radical cations from various substrates.
Production of Xe(g) and LiF(s) as byproducts.
Abstract
The feasibility of employing the XeF2/2LiAl(ORF)4 (ORF = OC(CF3)3) system as a deelectronator, formally generating Xe(g) + 2 LiF(s) + 2 ▢+, was investigated. While this proved successful for substrates...