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January 1, 2026Chemical ScienceOpen Access

Using Xenon Difluoride and 2 Li[Al{OC(CF3)3}4] as an Oxidant: From Organoxenonium Intermediates to (Fluoro-)Biphenyl Radical Cations

Konstantin Kloiber Tim Heinzmann Benoît Lacombe Philipp Thielert Malte Sellin Tim Schwandt Sabine Richert Stefan Weber Ingo Krossing

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Key Points

To evaluate the potential of the XeF2/2Li[Al(ORF)4] system as a deelectronator.
Investigated the reaction system XeF2/2Li[Al(ORF)4] as an oxidant.
Analyzed the generation of organoxenonium intermediates.
Examined the formation of radical cations from substrates.
Successful generation of radical cations from various substrates.
Production of Xe(g) and LiF(s) as byproducts.

Implication

Experimental investigation reveals substrate interactions with Xenon Difluoride for radical cation generation.

Discussion

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Cite This Study

Kloiber et al. (2026) studied this question.

synapsesocial.com/papers/69fbe382164b5133a91a2cf7 https://doi.org/10.1039/d6sc01402j

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