This research reveals macrocycles enhance photoluminescence and catalyze dealkylation in tertiary amines, suggesting diverse applications.
-pyriporphyrin. The resulting macrocycles exhibit interesting conformational dynamics, analyzed using nuclear magnetic resonance (NMR) and circular dichroism (CD) spectroscopy. Further studies revealed that they act as ligands, coordinating to metal ions, including palladium(II) and ruthenium(II). Additionally, thiophene-containing derivatives and their ruthenium complexes exhibit photoluminescence properties. The palladium complexes of both macrocycles catalyze the dealkylation of tertiary amines.
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Kamyszek et al. (2026) studied this question.
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