Analysis reveals that ammonium formation occurs through dismutation in a molybdenum complex, implying an efficient catalytic route.
Mechanism of functionalization of the MoN bond of a Mo (VI) [(OCO)Mo(N)Cl] complex, by two protons and electrons, into the Mo–NH 2 complex occurs via dismutation. Subsequent protonation readily liberates ammonia.
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Personeni et al. (2026) studied this question.
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