Aging effect and large recoverable electrostrain in Mn-doped KNbO3-based ferroelectrics

K Nb O 3 -based ferroelectrics have drawn much attention in recent years owing to their good piezoelectric performance among Pb-free piezoelectrics. However, little is known about the aging effect of these materials. In the present study, the authors systematically studied the aging effect of a Mn-doped (K0.99Li0.01)(Nb0.65Ta0.35)O3 ceramic with an aim to find an aging-induced recoverable electrostrain effect based on a reversible domain switching mechanism. They found that aging in the ferroelectric state made the otherwise normal hysteresis loop into a double loop, and more interestingly the aged sample demonstrated a large recoverable electrostrain of 0.125% at 4kV∕mm in an unpoled state. Such a behavior persisted up to 140°C and showed good recoverability. The aging-induced double hysteresis and recoverable electrostrain suggest a reversible domain switching mechanism due to a symmetry-conforming short-range ordering of point defects. The striking similarity of the aging effect between acceptor-doped A+B5+O3 and acceptor-doped A2+B4+O3 systems indicates a common physical origin of aging.