Mechanochemical Transformation From Zigzag‐Type Layered/Phenakite to Disordered Rocksalt in Mn‐Rich Cathodes for Li‐Ion Batteries

. Systematic structural and electrochemical comparisons across the LMMOF series further reveal how progressive disorder and phase mixing reshape Li-ion transport pathways. Together, these results establish a mechanistic framework for leveraging dopant- and structure-controlled precursor chemistry to direct mechanochemical DRX formation, and they offer a design principle for earth-abundant, Mn-rich DRX cathodes with tunable disorder.