Distorted to Pentacoordinated Carbon- Convex Platonic Molecular Relationships

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Key Points

The review aims to examine the structural characteristics and strain energies of tetrahedral carbon compounds.
Review of molecular structures and strain energies of tetrahedrane, cubane, and dodecahedrane.
Discussion of isolable derivatives and their stabilization mechanisms.
Exploration of reactions and properties related to substituted derivatives.
Cubane and dodecahedrane are found to be stable molecules, while tetrahedrane remains elusive.
Sterically stabilized tetra-tert-butyltetrahedrane and various derivatives have been successfully isolated.
Electron affinity of perfluorododecahedrane is comparable to that of F2, showcasing significant chemical behavior.

This review explores the structures and properties of tetrahedrane and its derivatives, highlighting implications in molecular chemistry.

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Lee‐Ruff et al. (2026) studied this question.

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