Polyelectrolyte multilayers deposited by sequential spraying of poly(styrenesulfonate) and poly(diallyldimethylammonium) solutions are described. A highly uniform thin film is rapidly obtained over a large area. The morphology, uniformity, and chemical composition of sprayed multilayers, as well as the selective membrane properties, are found to be virtually identical to those prepared by dip-immersion.
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Schlenoff et al. (2000) studied this question.
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