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is proved to be thermally stable. Spiro-MeOTAD with additives was crystallized at 85 °C due to a low glass transition temperature, and hole mobility was significantly deteriorated, which was responsible for the thermal instability. Thermal stability was significantly improved for the inverted structure with the NiO hole transporting layer, where the power conversion efficiency (PCE) was maintained at 74% of its initial PCE of 14.71% after the 80th thermal cycle (one cycle: heating at 85 °C for 2 h and cooling at 25 °C for 2 h). This work implies that the thermal stability of perovskite solar cells depends on selective contacts.
Zhao et al. (Fri,) studied this question.