This review summarizes the progress made essentially these last ten years on heterogeneous palladium catalysis in pure water. The work covers four important palladium‐catalyzed transformations for carbon‐carbon bond formation: Suzuki, Heck, Sonogashira and Tsuji–Trost reactions. The discussion focuses on the efficiency and reusability of the heterogeneous catalysts as well as on the experimental conditions from a sustainable chemistry point of view. The review is introduced by a discussion on mechanistic aspects inherent to heterogeneous catalysis.
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Lamblin et al. (2010) studied this question.