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April 17, 2001Angewandte Chemie International Edition

Catalytic Asymmetric Synthesis of Epoxides from Aldehydes Using Sulfur Ylides with In Situ Generation of Diazocompounds

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] (0.5 mol %).

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Aggarwal et al. (2001) studied this question.

synapsesocial.com/papers/6a00499e4716aad0cc85a32d https://doi.org/10.1002/1521-3773(20010417)40:8<1430::aid-anie1430>3.0.co;2-w

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Also Consider

Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1A Simple Method for Generation of Diazocompounds in an Aqueous Two-Phase SystemOriginal Research · 1978 · 24 citations
2A Simple Method for the Synthesis of Substituted Benzylic Ketones: Homologation of Aldehydes via the in Situ Generation of Aryldiazomethanes from Aromatic AldehydesOriginal Research · 2000 · 47 citations
3Diastereoselectivity in the Diels-Alder reactions of thio aldehydesOriginal Research · 1988 · 79 citations
4Realisation of highly stereoselective dihydroxylation of a cyclopentene in the synthesis of (−)-aristeromycinOriginal Research · 1999 · 12 citations
5Catalytic Asymmetric Epoxidation of Aldehydes. Optimization, Mechanism, and Discovery of Stereoelectronic Control Involving a Combination of Anomeric and Cieplak Effects in Sulfur Ylide Epoxidations with Chiral 1,3-OxathianesOriginal Research · 1998 · 127 citations