Full(erene) of surprises: The first isomerically pure multi-hydroxylated fullerene, C60(OH)8, shows a reduction peak and a reoxidation peak in aqueous solution. With surprising catalytic performance in the hydrogen evolution reaction (HER), when electrodeposited on a glassy carbon electrode (GCE), salts of C60(OH)8 may prove to be effective molecular catalysts for conducting the HER without transition metals.
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Zhuo et al. (2013) studied this question.
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