The 363.8 nm (3.408 eV) photoelectron spectrum of the NH2 (X̃ 2B1)+e−←NH−2(X̃ 1A1) transition of the amide anion is reported. The electron affinity of amidogen is found to be EA(NH2) =0.771 ±0.005 eV. P, Q, and R rotational branches are observed in the spectrum; a simple model which accounts for the band structure is presented.
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Wickham-Jones et al. (1989) studied this question.
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