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December 5, 2010Angewandte Chemie International Edition185 citations

Highly Efficient Extraction of Sulfate Ions with a Tripodal Hexaurea Receptor

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CJChuandong JiaMinistry of Education of the People's Republic of ChinaBWBiao WuShanghai UniversitySLShaoguang LiChina University of Geosciences

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Abstract

Fatal extraction: The Hofmeister bias for sulfate ions in aqueous environments can be overcome by using a tripodal hexaurea receptor (L) that completely encapsulates the sulfate ion in a complementary cavity protected by hydrophobic aromatic rings (see picture; C gray, N blue, O red, S yellow). Almost quantitative extraction of sulfate ions from an aqueous to an organic phase is achieved when this receptor is used as a liquid–liquid extractant.

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Cite This Study

Jia et al. (2010) studied this question.

synapsesocial.com/papers/6a013f64831589f3542e0ceehttps://doi.org/10.1002/anie.201004461
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