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January 1, 1998Chemical Communications

First synthesis of a C-glycoside anologue of a tumor-associated carbohydrate antigen employing samarium diiodide promoted C-glycosylation

Dominique Urban Troels Skrydstrup Jean‐Marie Beau Troels Skrydstrup

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Abstract

A hydrolytically stable analogue of the Tn antigen has been efficiently synthesized for the first time employing a SmI2-promoted coupling of the pyridyl sulfone of N-acetylgalactosamine with an aldehydoamino acid derivative.

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Urban et al. (1998) studied this question.

synapsesocial.com/papers/6a0166e24716aad0cc861175 https://doi.org/10.1039/a801196f

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