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Transition metal nanoclusters are highly selective and active catalysts. To allow for ease of recycling, Pd nanoclusters were supported on SiO2/Fe2O3 magnetic nanocomposites. Pd/HS-SiO2/Fe2O3 and Pd/H2N-SiO2/Fe2O3 were examined for the hydrogenation of nitrobenzene. Pd/H2N-SiO2/Fe2O3 showed excellent reactivity, with a conversion rate that was ∼5 times higher than commercial Pd/C catalyst.
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Yi et al. (2006) studied this question.
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