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The standard oxidation-reduction potential of the system of Mn(II)EDTA-Mn(III)EDTA complexes has been determined to be E°MnY=0.579V. vs. SCE from the potentiometric measurement with the rotated platinum electrode. From this value the logarithmic stability constant of the Mn(III)EDTA complex (logKMn(III)Y) has been calculated to be 24.9 at 25.0°C and μ=0.2.
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Tanaka et al. (1965) studied this question.
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