Ionic Liquid‐Assisted Crystallization and Defect Passivation for Efficient Perovskite Solar Cells with Enhanced Open‐Circuit Voltage

on surfaces and at grain boundaries of the perovskite film could also be reacted by DMII, leading to the reduction of recombination centers and trap states. On the other hand, the DMII ionic liquid with a "Ostwald ripening effect" could retard the crystallization process of perovskite crystals and yield better film quality with higher crystallinity, smoother morphology and larger grains. As a result, the optimal device achieved a champion power conversion efficiency (PCE) of 20.4 %. Particularly, the modified devices demonstrated a significant elevation in open-circuit voltage from 1.03 to 1.10 V. The hydrophobicity of perovskite films modified by DMII was enhanced and the un-encapsulated DMII devices retained 91 % of their initial PCE after aging 60 days under 15±5 % relative humidity.