The Use of Fluorinated Alkoxide Ligands in ∼ D 3h Compounds Increases Co Electrophilicity and Eases Co(III)/Co(II) Oxidation

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This research aims to explore how fluorinated alkoxide ligands affect the electrophilicity of cobalt compounds and their oxidation states.
Evaluated co electrophilicity in fluorinated alkoxide complexes.
Compared co(iii)/co(ii) reduction potentials with related fluorinated analogs.
Analyzed structural properties in d3h compounds.
Increased co electrophilicity observed with fluorinated alkoxide ligands compared to non-fluorinated counterparts.
Easier oxidation between co(iii) and co(ii) states was noted, facilitating redox reactions.

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Demonstrates increased co electrophilicity and eased co(iii)/co(ii) oxidation in fluoride compounds, suggesting potential chemical applications.

) in the Co(III)/Co(II) reduction potential versus related fluorinated analogs.

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Bussiere et al. (2026) studied this question.

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