AB - EL, una storia innocente

In this paper, we present an overview of results in the literature regarding the thermodynamical scaling of the dynamics of liquids and polymers as measured from high-pressure measurements. Specifically, we look at the scaling exponent γ and argue that it exhibits the limiting behavior γ → 4 in regimes for which molecular interactions are dominated by the repulsive part of the intermolecular potential. For repulsive potentials of the form U(r) ∝ r-n, γ has been found to be related to the exponent n via the relation γ = n/3. Therefore, this limiting behavior for γ would suggest that a large number of molecular systems may be described by a common repulsive potential U(r) ∝ r-n with n ≈ 12.