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Vinylene or ethynylene linkers in the bridging ligands of photofunctional multinuclear complexes synthesized by various coupling reactions, such as the Mizoroki-Heck reaction, olefin metathesis, and Sonogashira coupling, were successfully converted to their corresponding saturated carbon chains using photochemical hydrogenation, which proceeded in an MeCN-pyridine-CF
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Yamazaki et al. (2016) studied this question.
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