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January 1, 2004Chemical Communications182 citations

VIII (OH) O2C–C6H4–CO2. (HO2C–C6H4–CO2H) x (DMF) y (H2O) z (or MIL-68), a new vanadocarboxylate with a large pore hybrid topology: reticular synthesis with infinite inorganic building blocks?

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KBK. BartheletJMJérôme MarrotGFG. Férey

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Abstract

V(III)(OH)O(2)C-C(6)H(4)-CO(2).(HO(2)C-C(6)H(4)-O(2)H)(x)(DMF)(y)(H(2)O)(z) or MIL-68 was solvothermally synthesised in a non-aqueous medium. Its structure, built up from octahedral chains connected by terephthalate linkers, exhibits large hexagonal channels containing different occluded moieties. Their irreversible removal releases a specific surface area of 603(22) m(2).g(-1)(BET).

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Cite This Study

Barthelet et al. (2004) studied this question.

synapsesocial.com/papers/6a06565f4d64b923af16db24https://doi.org/10.1039/b312589k
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