Improved Performance of VOx‐Coated Li‐Rich NMC Electrodes

A VO x coating of Li 1.2 Mn 0.56 Ni 0.16 Co 0.08 O 2 , made through a low‐temperature annealing process (350 °C), results in the formation of a protecting layer, which enables electrodes to be prepared with an aqueous binder, offering a significantly improved electrochemical performance. The comparison with uncoated electrodes demonstrates the significantly improved performance of VO x ‐coated Li 1.2 Mn 0.56 Ni 0.16 Co 0.08 O 2 , which substantially outperforms the uncoated material by 30 mAh g −1 at moderate rates. The VO x coating is found to prevent the contact of Li 1.2 Mn 0.56 Ni 0.16 Co 0.08 O 2 with water from the aqueous‐binder processing, preventing leaching of metal cations. Upon cell operation, the coating delays the transformation of the active layer material into the spinel phase, occurring at low voltages, thus delaying its typical capacity fade upon cycling. Finally, the coating contributes to the overall material capacity, while ensuring the lithium deintercalation and intercalation processes.